Use OpenVPN only with selected programs

Hello,

I would like to connect to an OpenVPN server with Debian 7 being the client and NOT route all traffic through it automatically. Then I would like to bind individual programs to the VPN network adapter (bind to IP of tun?).

Is that possible? I have been looking, but couldn't find any how-to. I also do not really know anything about iptables/network/etc, so I would really appreciate some help.

Thanks. :)

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